How to oxidize brass and copper to that gorgeous brown color.

How do I get that gorgeous brown patina on copper or brass?

There are actually several ways to get that gorgeous brown patina on your copper or brass. You can use chemicals or more eco-friendly methods. Some chemicals can be caustic and must be used with care. One chemical that I use is household clear ammonia. Ammonia works on Copper and Brass. One of the eco-friendly methods I use for Copper (and Sterling Silver) is hard boiled eggs. Then of course there are the more common chemicals such as Liver of Sulphur, Black Max (which contains hydrochloric acid and tellurium), and an antique solution that contains iron nitrate.

Copper and Brass Patinas Examples

Here are some jewelry pieces that I have oxidized using many of the methods I will describe.

curated content from Flickr

The Hard Boiled Egg Method

An Eco-friendly way to oxidize/patina Copper and Sterling Silver

A safe and eco-friendly oxidization process can be accomplished in about 4 - 6 hours. Here is what you need:

2 - 3 Hard Boiled Eggs ( at least 5 minutes, the yoke should be solid)
Small shallow dish to place your metal, jewelry pieces on
Plastic container with a tight fitting lid or Ziploc Bag that the small dish will easily fit inside with more than enough room for the hard boiled eggs.

Chop the two or three hard boiled eggs. Place your metal or jewelry pieces on the small dish. Add the chopped hard boiled egg to the plastic container or Ziploc bag. Place the small dish in the middle of the plastic container or inside the Ziploc Bag. The egg should not touch the metal or jewelry pieces. Cover with the lid or close the Ziploc Bag. Leave it alone! You will be tempted to look but don't! Using a Ziploc bag or a clear plastic container will help with this. You can open the container or Ziploc bag when the metal or jewelry pieces darken to the color you want. Throw away the eggs and shine your piece leaving some of the detail oxidized.

Using Household Ammonia for Copper and Brass

This is more like fume oxidation.

Using household ammonia is really quite easy and is an inexpensive way to oxidize copper and brass. I have tried this method on finished pieces that included freshwater pearls and turquoise which are usually considered delicate materials. All you need is a clean pickle jar with a lid, a piece of wire or fishing line to suspend your piece and clear ammonia. It is a little smelly but if you are quick it should be no problem. At no time should the metal or finished jewelry come in physical contact with the ammonia. It is the fumes that will produce this patina. I do not know the scientific reason why, I just know it works!

First and foremost, clean your piece of brass or copper with either alcohol or acetone to remove any oils or dirt so that the patina is consistent throughout the piece. Do not touch the surface that you want patinated.

Pour about 1 inch of Ammonia in a pint or quart size glass jar.

You can use wire or fishing line to suspend the metal or piece of jewelry just below the mouth of the jar. I taped the ends of two pieces of fishing line to the outside of the jar to create a little cradle. At no time should the metal or finished piece come in physical contact with the Ammonia.

Screw on the lid and wait a couple hours. You can check the piece to see what color you want to stop at.

There will not be any Ammonia odor to your piece but if you want you can leave it out for a while and very gently buff out any high points for contrast.

That's it!

Using Chemicals - Safety First!

(Or the non-ecofriendly way!)

Of course you can use the tried and true method of adding a patina to your metal with the use of Liver of Sulphur, Black Max, Antique Patina Solution, etc. There are a few chemicals that can be caustic and must be handled with care during the process of patination and disposal of application materials. I must admit I do use both depending on the kind of time I want to spend and what I have readily available. Here are some safety tips:
Make sure that you have a well ventilated area to work in.
Your work surface should be cleared off and paper should be laid down because accident do happen.
Always have a cup or bowl of clean water at the ready as well as a bowl of water with a little baking soda mixed in. I usually take old coffee mugs and fill them up about halfway and add about a teaspoon of baking soda.
Paper towels or old tshirts or clean rags should also be ready in case of spills or to dry off your pieces after you rinse off the chemical that you use.
Safety Glasses - Yes no one likes to wear them but are you willing to jeopardize your eyesight for one accidental splash? I think not!
Rubber/nitrile gloves - I prefer nitrile as they are a bit thicker and sturdier than the thin latex or plastic gloves. They do cost more but I reuse them as many times as I can before they break. I just wash my hands with the gloves on when I am done and pat them dry with clean old towels before I take them off.

Water Water Water - I personally like to use running water when I can but when I teach classes it is not always possible so a gallon jug of water is always at the ready!

Materials List

What you should have on hand when you patina metal.

Cotton Swabs/Cotton Balls/Cotton Pads
Brass Brush (This can get wet)
Stainless Steel Brush (This shouldn't get wet)
Green Scrubbie pads ( My favorite brand is the 3M. These are the ones that you use for scouring your dishpans. You can find them at any grocery store
ProPolish Pads (These are spongy pads that contain permanently bonded micro-abrasives. They are used to shine up the highlighted areas of your patinated pieces. You can purchase these at most online jewelry supply/bead shops.

Link List

Helpful links to find what you need!

I have listed a few online shops to find some of the tools mentioned in this lens as well as where to find me!
Delia's Delight Jewelry
This is my website where I sell my wares, how you can find me selling my wares and when you can learn to make your own wares!
Pro Polish Pads
You can find Pro Polish Pads here. This is a great one stop shop for all your beading needs. I love their Crystal Mixes.
Cool Tools' Patina Gel
This is my favorite form of Liver of Sulphur because it is so versatile. I can use it straight from the bottle with a paint brush or cotton swab to apply it directly where I want or can dilute it in hot water to dunk the whole piece. Actually this website has alot of "cool tools" for jewelry making especially metal clay!
Reactive Metals - Antique Patina for Copper and Brass
This is hands down the best and fastest patina solution for copper and brass. A little goes a long way so use it very sparingly. I usually dip a cotton swab in water and then place a drop or two of this solution on the swab and rub it on the piece I want to patina. It works best when the metal is very clean and warm. Reactive Metals also sells other patina solutions for Shibuichi, Shakudo, and Mokume Gane.

Monica's Monologue

Come visit my blog for my jewelry making adventures!
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Reader Feedback

Did you try this method? Did it work for you? Let me know!

  • Grimasa May 18, 2012 @ 12:00 pm | delete
    Very nice post! One question though - is it possible to "cure" the oxidation layer? that is - i used the egg method on my brass-copper jewelry and in the morning it looked veeery nice, brownish brass and almost black copper, but when i touched it with my fingers the black oxide which was on the copper cleaned away from the piece leaving it just a bit darker, but far away from that amazing black effect before. I understand that it can be desirable effect when the jewelry is hammered, spinned or has other irregular forms, because part of oxide goes away and part stays, but mine was flat and perfectly polished. I would like to be able to treat exide in some way to fix the color. How can i do it?
  • deliasdelight May 25, 2012 @ 12:30 pm | delete
    I have had that happen but only when I used Liver of Sulphur. I usually lightly sand the surface with either a green scrubbie pad or fine grit sponge prior to oxidizing as it will give the metal some tooth to hang on to the oxidation. Also make sure that the copper or brass is clean, even though it maybe polished, it might not be clean from any polishing compound you may be using. You can use any number of clear fixatives to seal in the color such as Future floor polish (crazy as it sounds, it is basically a very thin acrylic sealer, use a paint brush) or a spray acrylic fixative. Keep in mind though that when you apply an acrylic layer, any irridescent color you have achieved will dull because you are covering it with an acrylic. Hope this helps.
  • AJTivol Apr 15, 2012 @ 8:08 pm | delete
    How nice to see such a thorough list of safety gear and supplies -- I never think to pull these things together until I'm mid-mess and then I'm scrambling. Now I can just put most of these things together in a kit with a list of everything I need and I'll always have what I need at hand. Nicely done.
  • Desiree Mar 12, 2012 @ 9:10 pm | delete
    could you please tell me which method warranted that beautiful gold color on the bracelet and the turquoise necklace? We just bought an old copper sink and I cleaned it with "bar keepers friend" and It completely lost all of it's patina! :( It doesn't match the faucet anymore, which is the exact brown on those two pieces of jewelry. Thank you so so much!
    Desiree
  • deliasdelight Apr 16, 2012 @ 8:01 am | delete
    You can try the Fuming method first to see if that works. My inlaws had the same issue everytime they cleaned the sink. It will get back to a patina eventually. When cleaning try using a solution of water, a little white vinegar and a couple of drops of antibacterial hand or dish soap. Apply it with a spray bottle and use a soft sponge. Good Luck!
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Jewelry Artisan and Instructor. I am a wife, mother of two and my passions are music, a good crime novel and making and teaching Jewelry!

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