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The Arrancar arc episodes 

110. Reopening of the Substitute Business! The Terrifying Transfer Student

January 10, 2007

In Hueco Mundo, the hollow Grand Fisher transforms into an imperfect arrancar and makes his way to the human world. Meanwhile, Shinji Hirako enrolls at Ichigo's school. During a routine hollow purification, Ichigo is confronted by Shinji, who shows that he can willingly produce a hollow mask just like Ichigo has done unconsciously on occasion. He asks Ichigo to join his group: the vizard. At the same time, Kon (inhabiting Ichigo's body) is attacked by Grand Fisher and Ury%u016B is attacked by another imperfect arrancar. Ury%u016B is rescued by his father, who reveals himself to be a Quincy, while Kon remains helpless against Grand Fisher.

111. Shock! The True Characters of the Fathers

January 17, 2007

After rescuing Ury%u016B from the arrancar attacking him, Ry%u016Bken offers to restore his powers provided he never again associates with the shinigami. Meanwhile, Kon is still running through town in an attempt to evade Grand Fisher. Despite receiving help from Ririn, Kuroud, and Noba, he is eventually caught. Just as he is about to be killed, Isshin Kurosaki steps in to save him, dressed in shinigami clothing. Both Ichigo and Shinji become aware of a new presence, though neither are able to identify it as Isshin. Curious, Ichigo decides to leave in order to check it out, but not before turning down Shinji's invitation. After a short conversation between Grand Fisher and Isshin, during which Isshin makes it clear that he's been aware of Kon, Ririn, Kuroud, and Noba as well as Ichigo's shinigami activities, Grand Fisher transforms into a larger version of himself and draws his zanpakut%u014D whilst mocking Isshin. Isshin casually identifies him as an arrancar and dispatches him in a single attack.

112. The Commencement of War, Vizard and Arrancar

January 24, 2007

With the death of Grand Fisher, Urahara appears to have a short chat with Isshin. The two talk about the plans of both Aizen and the vizard, more aware of the former than the latter. Both are aware of the vizard's interest in Ichigo. After they sense Ichigo approaching, they depart to avoid being seen. Things in Soul Society are also becoming tense, though what is causing it is unclear. At school, Shinji is still following Ichigo. When Ichigo confronts him, Shinji admits that he won't give up until Ichigo agrees to join the vizard. The offer is equally out of concern for Ichigo as it is for the vizard. Shinji explains that Ichigo's inner hollow will eventually overpower him, destroying everything he cares about. Later on, Shinji is confronted by Hiyori Sarugaki, a fellow vizard, about his lack of progress. They are interrupted by Chad and Inoue, who want to know what the two want with Ichigo. Hiyori states that it is none of their business, and prepares to kill Chad and Inoue. Shinji grabs her and runs away to prevent any such thing from happening. At the Karakura hospital, Ury%u016B formally asks Ry%u01D4ken for his own Quincy powers, swearing not to further affiliate with the shinigami.

113. Prelude to the Apocalypse, The Arrancar's Attack

January 31, 2007

After his chat with Shinji, Ichigo realizes that his inner hollow is indeed becoming more than he can control. Meanwhile, two arrancar (Yammy and Ulquiorra) arrive in Karakura Town, making a spectacular crater at their landing site. When everyone comes to see what happened, Yammy begins sucking the souls from everyone in the immediate area. Only Tatsuki Arisawa survives, and is left weakened as a result. Chad and Orihime arrive to save Tatsuki, but are easily repelled by Yammy, whose strength is great enough to bat Chad away in a single attack and reduce Tsubaki (Orihime's attack spirit) to pulp merely by blocking it. Before he can kill either of them, however, Ichigo arrives to save them.

114. Reunion, Ichigo and Rukia

February 7, 2007

Ichigo starts his battle with Yammy, blocking Yammy's first attack and cutting off his arm. However the fight is cut short when his inner hollow interferes, allowing Yammy to gain the upper hand. Before he can kill anyone present, however, Urahara and Yoruichi arrive to take over the battle. Yammy is no match for them, and is rescued by Ulquiorra, who then retreats in Hueco Mundo. Back at Ichigo's school, a team of shinigami is dispatched in response to the ever increasing arrancar threat. The team consists of Renji Abarai, T%u014Dshir%u014D Hitsugaya, Rangiku Matsumoto, Ikkaku Madarame, Yumichika Ayasegawa and Rukia Kuchiki, all of whom are posing as new students at Ichigo's school.

143. Revival of Grimmjow

October 3, 2007

After being brought before Aizen, Orihime is asked to demonstrate her power by restoring Grimmjow's arm. Upon doing so, Grimmjow asks her to restore his tattoo. With that done, he quickly kills Luppi to regain his rank. Though worried that her actions might only cause more fighting, Orihime resolves to make herself useful until Soul Society has prepared for the upcoming war. Meanwhile, Ichigo, Sado, and Ury%u016B make their way in Hueco Mundo. Along the way, Ury%u016B reveals why he is breaking his promise to his father not to associate with shinigami; since Ichigo is a shinigami substitute and has been abandoned by Soul Society, he doesn't consider Ichigo one of them.